IR analysis of borate glasses containing three alkali oxides
نویسندگان
چکیده
منابع مشابه
Mechanical Properties of Alkali Borate Glasses
A GLASS is, formally, a solid that solidifies without a well-defined melting point— defined as a singular temperature at which there occurs a discontinuous change in a physical property, for example specific volume, during transition between a liquid state and its corresponding solid state—but instead exhibits a continuous change in that property over a range of temperature. Glasses tend to inh...
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In this paper we re-examine the alkali dependence of the fraction of four-coordinated borons (N4) in two series of glasses: alkali borates (0·4M2O.B2O3) and mixed lithium caesium borates (0·4(xLi2O+(1-x)Cs2O). B2O3). High field B MAS-NMR experiments were performed to maximise the accuracy of the present results. We found no evidence for an alkali dependence on N4 in either system. In each case ...
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Since the discovery of fast ionic conductivity in glasses, there has been a large interest in explaining the diffusion mechanism. With this knowledge one may be able to design new glasses with optimized properties for various applications. It is well known that the ionic conductivity increases rapidly when a network glassformer is modified by the addition of a metal alkali. Despite considerable...
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Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...
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A lithium bismuth borate glass system is prepared by the conventional melt quenching technique. The Powder X-Ray diffraction analysis of the prepared samples confirms the amorphous nature of the samples. The density and molar volume studies report the change of structure with the increase of bismuth content. The FTIR analysis of the samples revealed that the network structure of the prepared sa...
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ژورنال
عنوان ژورنال: ScienceAsia
سال: 2013
ISSN: 1513-1874
DOI: 10.2306/scienceasia1513-1874.2013.39.278